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The conditional acid dissociation constants (pKa′) of two sulfonephthalein dyes, thymol blue (TB) and m-cresol purple (mCP), were assessed throughout the estuarine salinity range (0<S<40) using a tris/tris–HCl buffer and spectrophotometric measurement. The salinity dependence of the pKa′ of both dyes was fitted to the equations (25 °C, total proton pH scale, mol kg soln−1):The estimated accuracy of pH measurements using these calculated pKa′ values is considered to be comparable to that possible with careful use of a glass electrode (±0.01 pH unit) but spectrophotometric measurements in an estuary have the significant advantage that it is not necessary to calibrate an electrode at different salinities. pH was measured in an estuary over a tidal cycle with a precision of ±0.0005 pH unit at high (S>30) salinity, and ±0.002 pH unit at low (S<5) salinity. The pH increased rapidly in the lower salinity ranges (0<S<15) but less rapidly at higher salinities. 相似文献
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Shane M. Ohline Malcolm R. Reid Shamus L.G. Husheer Kim I. Currie Keith A. Hunter 《Marine Chemistry》2007
Accurate measurement of seawater pH has long been sought by marine chemists (for example: [Dickson, A.G. 1993a. The measurement of sea water pH. Marine Chemistry, 44, 131–142, Dickson, A.G. 1993b. pH buffers for sea water media based on the total hydrogen ion concentration scale. Deep-Sea Research, 40, 107–118; Zhang, 1996; Tapp, M., Hunter, K.A., Currie, K. and Macaskill, B. 2000. Apparatus of continuous-flow underway spectrophotometric measurement of surface water pH. Marine Chemistry 72(2–4), 193–202; Friis, K., Koetzinger, A., Wallace, D.W.R. 2004. Spectrophotometric pH measurement in the ocean: Requirements, design and testing of an autonomous charge-coupled device detector system. Limnology and Oceanography: Methods 2, 126–136]. Recently, such attempts have taken on greater significance as anthropogenic carbon dioxide emissions may create rapidly changing oceanic pH. Spectrophotometric techniques have been accepted generally as the best for determination of seawater pH. Here we report a new technique using thymol blue as the indicator dye and fitting the entire spectrum from 400 to 900 nm rather than measuring the absorbance values at only two or three points in the spectrum. This full-spectrum modelling enables a reduction in signal to noise over other techniques. In the laboratory, we find with seawater samples a pH precision increase of five-fold “within” a sample and seven-fold “between” samples when comparing the full spectrum to the three-point method of analysis [Zhang, H., Byrne, R.H. 1996. Spectrophotometric pH measurements of surface seawater at in-situ conditions: absorbance and protonation behaviour of thymol blue. Marine Chemistry 52, 17–25]. 相似文献
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Philip M. Marren Shamus C. Toomath 《Boreas: An International Journal of Quaternary Research》2013,42(1):57-70
This study describes changes to the proglacial drainage network of Skaftafellsjökull, Iceland from 1998 to 2011. Proglacial landscapes are highly sensitive to glacier retreat, and the retreat of glaciers around the world has accelerated since the mid‐1990s. Skaftafellsjökull has retreated at an average rate of 53 m per year since 1999. From 1999 to 2003, the river incised and formed a sequence of now abandoned channels and fluvial terraces extending ～1 km downstream from the glacier. Retreat of the glacier from an over‐deepened ice‐contact slope meant that there was a positive correlation between the distance of glacier retreat and the amount of fluvial incision. Incision was episodic, occurring annually in response to drainage reactivation and reorganization. On an annual basis, the rate of retreat is moderately negatively correlated with the rate of incision. This is partly because the ice‐contact slope decreases away from the position of maximum glacier extent, and also because more sediment is released with faster retreat, counteracting the effect of retreat down an ice‐contact slope. From 2003 onwards, proximal terrace formation ceased, as a proglacial lake became established. Downstream of the lake outlet further incision deepened the channel, with most change occurring during a flood in 2006, where incision in the upstream confined reach was accompanied by downstream aggradation and terrace formation. These observations indicate that proglacial changes in response to glacier retreat are a result of the interactions of river channel incision and terrace formation, aggradation, lake development, and flooding, which together control river channel changes, sediment redistribution and sandur stratigraphy. 相似文献
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Subsurface video footage can be used as a successful identification tool for various marine organisms; however, processing of such information has proven challenging. This study tests the use of automated software to assist with photo-identification of the great white shark Carcharodon carcharias in the region of Gansbaai, on the south coast of South Africa. A subsurface photo catalogue was created from underwater video footage. Single individuals were identified by using pigmentation patterns. From this catalogue, two images of the head for each individual were inserted into automated contour-recognition software (Interactive Individual Identification System Beta Contour 3.0). One image was used to search the database, the other served as a reference image. Identification was made by means of a contour, assigned using the software to the irregular border of grey and white on the shark's head. In total, 90 different contours were processed. The output provided ranks, where the first match would be a direct identification of the individual. The method proved to be accurate, in particular for high-quality images where 88.24% and 94.12%, respectively, were identified by two independent analysts as first match, and with all individuals identified within the top 10 matches. The inclusion of metadata improved accuracy and precision, allowing identification of even low-quality images. 相似文献
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Two major river systems operated in southern and eastern England throughout the Pleistocene: the river Thames and the Solent river. Both rivers are axial streams of comparable size draining major basinal structures comprising similar Tertiary and Mesozoic rocks. Although the modem Thames flows broadly W-E in the London Basin, upstream of Reading it flows from the north to drain the south Midlands. It was diverted to its present course through London by glaciation in the Anglian (Elsterian) before which it flowed across East Anglia into the southem North Sea. The Solent river no longer exists since most of its course was drowned by eustatic sea-level rise during the Flandrian Stage (Holocene). Previously, it flowed eastwards across SE Dorset and S Hampshire as an extension of the modem river Frome in the Hampshire Basin. During periods of low sea-level (cold stages) it was a tributary of the 'Channel River'. Fluvial aggradations provide evidence of the former courses of these substantial rivers and their tributaries. The facies and sedimentary structures indicate that the bulk of the deposits in both systems accumulated in braided river environments under periglacial climates. Fossiliferous sediments provide biostratigraphical frameworks. During temperate periods the rivers adopted singlethread courses. Evolution of both rivers reflect their responses to climatic change, local geological structure and long-term tectonic activity. Both rivers are undoubtedly of considerable antiquity, their records potentially extend from the Early Pleistocene or Late Pliocene, but they may have originated in the early Tertiary. 相似文献
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Glacier retreat leads to changes in channel pattern during deglaciation, in response to changing water, sediment and base level controls. Recent ongoing retreat at Skaftafellsjökull, Iceland (c. 50 m per year since 1998) has resulted in the formation of a sequence of river terraces, and several changes in river channel pattern. This paper compares widely used models of river channel pattern against the changes observed at Skaftafellsjökull. Doing this reveals the role of topographic forcing in determining proglacial channel pattern, whilst examining the predictive power and limitations of the various approaches to classifying river channels. Topography was found to play a large role in determining channel pattern in proglacial environments for two reasons: firstly, glacier retreat forces rivers to flow through confined moraine reaches. In these reaches, channels which theory predicts should be braided are forced to adopt a single channel. Secondly, proximal incision of proglacial rivers, accompanied by downstream aggradation, leads to changes in slope which force the river to cross channel pattern thresholds. The findings of this work indicate that in the short term, the majority of channel pattern change in proglacial rivers is due to topographic forcing, and that changes due to changing hydrology and sediment supply are initially relatively minor, although likely to increase in significance as deglaciation progresses. These findings have implications for palaeohydraulic studies, where changes in proglacial channel pattern are frequently interpreted as being due to changes in water or sediment supply. This paper shows that channel pattern can change at timescales faster than hydrological or sediment budget changes usually occur, in association with relatively minor changes in glacier mass balance. Copyright © 2014 John Wiley & Sons, Ltd. 相似文献
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